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Synthesis of New Solid Polymer Electrolytes--TPL,
Inc., 3921 Academy Parkway North, NE, Albuquerque, NM 87109-4416; 505-342-4412
Dr. Tuqiang Chen,
Principal Investigator
Mr. H.M. Stoller,
Business Official
DOE Grant No. DE-FG03-00ER83114
Amount: $99,998
The
chemical and thermal instabilities of liquid electrolytes have hampered the
performance of lithium batteries in terms of power and energy density, cycle
and shelf life, and safety. While solid
polymer electrolytes (SPEs) have the potential to solve the problems, some of
their electrochemical properties, such as ionic conductivity, are not
satisfactory for high performance lithium batteries. TPL, Inc. proposes a new class of solid polymer electrolytes,
functional dendritic ionomers (FDIs), for lithium-based batteries. The FDIs have superior electrochemical
properties required for high performance lithium-polymer batteries, because of
significantly improved ionic transport and thermal stability. TPL, Inc. proposes to team with Sandia
National Laboratories (SNL) to demonstrate the feasibility of fabricating the
new SPEs. Cells will be made with the
new SPEs and evaluated by testing the electrochemical properties. The P.I. has extensive experience in
synthesis of functional dendritic polymers. SNL has extensive experience in lithium battery chemistry, test,
and evaluation.
Commercial
Applications and Other Benefits as described by the awardee: Lithium-polymer batteries have extensive
applications in commercial products including electric vehicles, radios,
telephones, televisions, video cameras, computers, tools, and other consumer
products. They have corresponding
applications for the Federal government in defense, spacecraft, and probes.