46
A
Metallic Interconnect for Intermediate Temperature, Planar, Solid Oxide Fuel
Cell Technology--Materials
and Systems Research, Inc., 5395 West 700 South, Salt Lake City, UT
84104; 801-530-4987
Dr.
Tad Armstrong, Principal Investigator, tarmstro@MSRlhome.com
Dr.
Dinesh K. Shetty, Business Official, dshetty@MSRlhome.com
DOE
Grant No. DE-FG03-00ER83044
Amount:
$650,000
Intermediate
temperature (<800C), planar solid oxide fuel cells (SOFC) require the
development of low-cost, oxidation-resistant, metallic interconnects.
Commercially available alloys are limited for this application because
they contain chromium, which oxidizes in both air and fuel, forming an
electrically resistive layer that slowly evaporates, lowering SOFC efficiency.
This project will develop suitable coatings that suppress oxidation
kinetics, suppress the volatilization of chromium oxide, and lower the overall
resistance, thus increasing efficiency.
In Phase I, thin (~2000 Angstroms) coatings of certain metals and oxides
were deposited on commercial nickel-based alloy and stainless steel foils.
The foils were oxidized in air and fuel, and their resistance was
measured both ex-situ (out of stack) and in-situ (in four cell
stacks). The coatings suppressed
the oxidation kinetics, and also lowered the net resistance.
Stack power at 800˚C was more than doubled by using coated
interconnects. Even more
importantly, the interconnect resistance decreased with time, and
correspondingly, stack power increased with time. In Phase II, the main focus will be on identifying coatings
that will be able to suppress the oxidation kinetics of low cost materials, such
as stainless steels, for several thousand hours while maintaining low resistance
and achieving a stack power density of ~1W/㎝2
using natural gas as fuel. Low-cost,
large volume methods for the deposition of coatings will be developed.
Several four-cell stacks, and one 1 kW stack will be tested for long
periods of time using coated interconnects exhibiting ultra-low resistance.
Commercial
Applications And Other Benefits as described by the awardee: The metallic
interconnects should allow for numerous applications of highly efficient solid
oxide fuel cells (SOFC) in distributed, residential, automotive, and portable
power. The devices would operate on
hydrocarbon fuels at high efficiency while creating negligible pollution.