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High Flux Ceramic Membrane for Hydrogen Separation

DOE Grant No. DE-FG03-98ER86077
Amount: $99,994


Small Business Research Institution
Harvest Energy Technology, Inc.
9253 Glenoaks Boulevard
Sun Valley, CA 91352-2614
Dr. K. Durai-Swamy, Principal Investigator
Dr. David Warren, Business Official
(818) 767-3157
California Institute of Technology
1200 East California Boulevard
MC 213-6
Pasadena, CA 91125


For electrical power generation, fuel cells that efficiently convert hydrogen to electrical power can reduce the emission of greenhouse gases. However, more economic methods to produce hydrogen from hydrocarbon fuels are needed. Advanced fuel processing systems are needed that incorporate high-temperature composite membranes to economically separate hydrogen from reformed fuels. While silica membranes are capable of selectively separating hydrogen from gas mixtures, they are not economic due to their low permeability. This project will develop a selective high temperature membrane having substantially increased permeance relative to current membrane technology. In Phase I, a novel composite membrane will be fabricated consisting of a macroporous alumina support, a mesoporous Vycor layer, and an ultra-thin permselective silica layer that is formed using a specialized chemical vapor deposition technique. The membrane will be tested for permeation characteristics using simulated reformed fuel gases, and an assessment will be made of the separator economics.

Commercial Applications and Other Benefits as described by the awardee: Economic ceramic membrane hydrogen separators should improve the efficiency of hydrogen production from reformed fuels and will assist in the commercialization of fuel cell technology.


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